Read |
Chapter 6 |
Take |
Notes from the board
[my notes are on this page] |
Notice |
figures 6.13, 6.19,
6.20, 6.21, 6.28 |
Notice |
figure 6.17 (wasn't
he suave?) |
Enjoy |
"Chemistry at Work"
on page 200 |
Check Out |
Schroedinger's
Cat (Thank you Caroline McNamara for the link) |
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Problems |
6.2, 6.6, 6.8abd |
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6.14, 6.18, 6.20 |
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6.24, 6.26, 6.28c,
6.32a[b] |
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6.40, 6.44b, 6.46 |
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6.54, 6.56 |
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6.64, 6.66abdf, 6.68 |
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Lab 31 |
Spectrophotometric
Determination of Iron |
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Other
Possible Labs: |
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Diffraction
Grating Calibration |
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Analysis
of Hydrogen Spectrum |
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Notes |
Define electromagnetic, spectrum |
Wave stuff: c, l,
n, nm, E = hn, c =
ln |
h = 6.63x10-34 J/Hz |
c = 3.0x108 m/s |
Frequency gives color |
UV, IR, visible, etc. |
Photons: energy packets - wave
AND particle properties |
"Quantum" & photoelectric
effect |
Line spectra, "n," emission
& absorption spectra |
equation 6.3
Bohr's model: equation 6.4
combined: equation 6.5 J
RH = 2.18x10-18 J = 313.6 kcal/mol
for Hydrogen: n=x to n=1 gives UV
n=x to n=2 gives visible
n=x to n=3 gives IR |
Electron: Wave? Particle?
"Wavicle!" |
DeBroglie: E = mc2
and E = hn and c = ln
combine to give
l = h/mv for any particle (v = velocity) |
Heisenberg & uncertainty
principle |
Wave functions, probability,
orbitals |
Quantum numbers & orbitals |
n = 1, 2,
3, ... |
energy level
("shell") |
l = 0, 1, 2,
...n-1 |
shape or # of nodes
("subshell") |
ml
= –l, –l+1...l–1, l |
orientation in space |
s = ±½ |
spin ("up" or "down") |
s, p, d, f orbitals
for l = 0, 1, 2, 3 |
"Degenerate" |
Single electron vs. many electron |
Screening effect |
Electron structure 1s22s22p63s1
etc. What atom is that? |
Periodic table & electron
structure |
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